Oxidation and crystallization of an amorphous Zr60Al15Ni25 alloy

Oxidation and crystallization of an amorphous Zr60Al15Ni25 alloy

The amorphous ternary metallic alloy Zr60Al15Ni25 was oxidized in dry oxygen in the temperature range 310 ±C to 410 ±C. Rutherford backscattering (RBS) and cross-sectional transmission electron microscopy (TEM) studies suggest that during this treatment an amorphous layer of zirconium-aluminum-oxide is formed at the surface. Nickel was depleted in the oxide and enriched in the amorphous alloy n...

Crystallization Kinetics Study in Al87Ni10La3 Amorphous Alloy

In this study, the crystallization behavior of melt-spun Al87Ni10La3 amorphous phase was investigated by using X-ray diffraction and non-isothermal differential thermal analysis techniques. The results demonstrated that the amorphous phase exhibited two-stage crystallization on heating, i.e., at first step the amorphous phase transforms into α-Al phase and at second step Al11La3 and Al3Ni inter...

Non-isothermal Primary Crystallization Kinetics of the Amorphous Fe85.3B11P3Cu0.7 Alloy

In the present research, the primary crystallization kinetics of the amorphous Fe85.3B11P3Cu0.7 alloy was analyzed using non-isothermal DSC measurements. The average and local activation energies, Ea, were determined by different isokinetic and isoconversional methods. The results obtained for activation energy in this research, show that due to the complexity of the primary crystallization pro...

Pressure effects on Al89La6Ni5 amorphous alloy crystallization

Crystallization kinetics of amorphous NiTi shape memory alloy thin films

The temperature dependence of the crystallite nucleation and growth rates is measured for amorphous NiTi thin films. Using transmission electron microscopy, crystallites are shown to nucleate homogeneously in the film and to grow in a channeling mode. A mechanism that suppresses heterogeneous nucleation is proposed. By manipulating nucleation and growth rates, grains as large as 60 lm can be ob...